Questions: What stretching frequencies (in cm^-1) are present in the structure below?
Transcript text: What stretching frequencies (in $\mathrm{cm}^{-1}$ ) are present in the structure below?
Solution
Solution Steps
Step 1: Identify the functional group
The structure shows a benzene ring attached to a dimethylamino group (-N(CH3)2). The key bonds we're interested in for IR stretching frequencies are the C-H bonds (sp2 hybridized carbons in the benzene ring and sp3 hybridized carbons in the methyl groups) and the N-H bonds (although there are none in this case, this is important to distinguish).
Step 2: Analyze the C-H stretches
Aromatic C-H stretches (from the benzene ring) typically appear above 3000 cm⁻¹. Aliphatic C-H stretches (from the methyl groups) appear below 3000 cm⁻¹.
Step 3: Consider the N-H stretches
There are no N-H bonds present in the molecule, so we won't see any N-H stretches (which would normally appear around 3300-3500 cm⁻¹).
Final Answer
3100 cm⁻¹ (and other values above 3000 cm⁻¹ for aromatic C-H stretches) and values below 3000 cm⁻¹ for aliphatic C-H stretches are present. So the answer is "all of these".