Since the calculated Chi-Square statistic \( 22.5037 \) is greater than the critical value \( 7.8147 \) and the p-value \( 0.0001 \) is less than \( \alpha = 0.05 \), we reject the null hypothesis.
\[
\boxed{\text{Reject } H_0: \text{ There is a significant difference in the distribution of working hours between private practice and hospital doctors.}}
\]