\[
\begin{aligned}
&\text{(a) Ge has the higher ionization energy.} \\
&\boxed{\text{Ge}} \\
&\text{(b) P has the higher ionization energy.} \\
&\boxed{\text{P}} \\
&\text{(c) Cl has the higher ionization energy.} \\
&\boxed{\text{Cl}} \\
&\text{(d) As has the higher ionization energy.} \\
&\boxed{\text{As}}
\end{aligned}
\]