Questions: Below are several constitutional isomers with the molecular formula C6H14. Which of these isomers will have the largest heat of combustion?
Transcript text: Below are several constitutional isomers with the molecular formula $\mathrm{C}_{6} \mathrm{H}_{14}$. Which of these isomers will have the largest heat of combustion?
Solution
Solution Steps
Step 1: Identify the Isomers
The given molecular formula is C8H18. The isomers shown are different structural arrangements of this formula.
Step 2: Understand Heat of Combustion
The heat of combustion is the energy released when a compound undergoes complete combustion with oxygen. For alkanes, the more branched the isomer, the lower the heat of combustion.
Step 3: Analyze the Structures
The first structure is a straight-chain alkane (octane).
The second structure is a branched alkane with one branch.
The third structure is a more highly branched alkane.
Final Answer
The straight-chain alkane (first structure) will have the largest heat of combustion because it is the least branched.