Boron (B) has 3 valence electrons. In BH4, boron is bonded to four hydrogen atoms, meaning it has 8 bonding electrons (4 bonds * 2 electrons/bond) and 0 non-bonding electrons.
Formal charge of B = 3 - 0 - 8/2 = 3 - 4 = -1
Step 2: Determine the formal charge of Hydrogen
Hydrogen (H) has 1 valence electron. In BH4, each hydrogen is bonded to the central boron atom, sharing 2 electrons in the bond. Each H has 0 non-bonding electrons.
Formal charge of H = 1 - 0 - 2/2 = 1 - 1 = 0
Step 3: Determine the overall charge
The overall charge of the BH4 ion is the sum of the formal charges of all the atoms.
Overall charge = (Formal charge of B) + 4 * (Formal charge of H)
Overall charge = -1 + 4 * 0 = -1