a. The moles of \(\mathrm{O}_{2}\) needed to react completely with 1.80 mol of \(\mathrm{C}_{2} \mathrm{H}_{2}\) is \(\boxed{4.50 \, \text{mol}}\).
b. The moles of \(\mathrm{C}_{2} \mathrm{H}_{2}\) needed to form 0.26 mol of \(\mathrm{CO}_{2}\) is \(\boxed{0.13 \, \text{mol}}\).