The results for the confidence intervals are as follows:
- The 95% confidence interval for the true mean pH of rainwater is \((4.73, 5.24)\).
- The 99% confidence interval for the true mean pH of rainwater is \((4.63, 5.34)\).
Thus, the final answers are:
- For part B: \(\boxed{(4.73, 5.24)}\)
- For part C: \(\boxed{(4.63, 5.34)}\)