The given equation is $100 = 4(2 + 3)$. To solve this, we need to simplify the right-hand side and check if it equals 100.
First, we simplify the right-hand side of the equation \(100 = 4(2 + 3)\).
\[ 4(2 + 3) = 4 \times 5 = 20 \]
Next, we compare the simplified right-hand side to the left-hand side of the equation.
\[ 100 \neq 20 \]
The equation \(100 = 4(2 + 3)\) is false.
\(\boxed{\text{False}}\)
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