We are tasked with finding \( \cos^{-1}\left(-\frac{\sqrt{3}}{2}\right) \). The value \( -\frac{\sqrt{3}}{2} \) indicates that we are looking for an angle whose cosine is negative.
Step 2: Determine the Reference Angle
The reference angle corresponding to \( \frac{\sqrt{3}}{2} \) is calculated as:
\[
\text{reference angle} = \cos^{-1}\left(\frac{\sqrt{3}}{2}\right) = \frac{\pi}{3}
\]
Step 3: Identify the Quadrants
The cosine function is negative in the second and third quadrants. Therefore, we need to find the angles in these quadrants that correspond to the reference angle.
Since \( \cos^{-1} \) returns the angle in the range \( [0, \pi] \), we select the angle from the second quadrant:
\[
\text{result angle} = \frac{2\pi}{3}
\]
Step 6: Convert to Degrees
To express the result in degrees:
\[
\text{result angle in degrees} = \frac{2\pi}{3} \times \frac{180}{\pi} = 120
\]
Final Answer
The angle whose cosine is \( -\frac{\sqrt{3}}{2} \) is:
\[
\boxed{\frac{2\pi}{3}} \quad \text{or} \quad \boxed{120^\circ}
\]