Questions: The strength of a covalent bond depends upon the size of the atoms and the bond order. In general short bonds are strong bonds.
For each pair of covalently bonded atoms, choose the one expected to have the higher bond energy.
(A) C=N
(B) C ≡ N
(A,B)
(C) C-C
(D) C ≡ C
(C,D)
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Transcript text: The strength of a covalent bond depends upon the size of the atoms and the bond order. In general short bonds are strong bonds.
For each pair of covalently bonded atoms, choose the one expected to have the higher bond energy.
(A) $\mathrm{C}=\mathrm{N}$
(B) $\mathbf{C} \equiv \mathrm{N}$
(A,B) $\square$
(C) C-C
(D) $C \equiv C$
(C,D) $\square$
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Solution
Solution Steps
Step 1: Understanding Bond Energy
Bond energy is the measure of bond strength in a chemical bond. It is the amount of energy required to break one mole of bonds in a substance in the gas phase. Generally, shorter bonds are stronger and have higher bond energies.
Step 2: Analyzing the First Pair
For the first pair:
(A) $\mathrm{C}=\mathrm{N}$ is a double bond.
(B) $\mathbf{C} \equiv \mathrm{N}$ is a triple bond.
Triple bonds are generally stronger and have higher bond energies than double bonds because they involve more shared electrons and are shorter.
Step 3: Analyzing the Second Pair
For the second pair:
(C) C-C is a single bond.
(D) $C \equiv C$ is a triple bond.
Again, triple bonds are stronger and have higher bond energies than single bonds due to the increased number of shared electrons and shorter bond length.