To determine the total number of valence electrons in $\mathrm{HNO}_{2}$, we first identify the elements and their respective valence electrons:
Next, we calculate the total number of valence electrons by summing the valence electrons of each atom in the molecule:
Now, we perform the arithmetic to find the total number of valence electrons: \[ 1 \times 1 + 1 \times 5 + 2 \times 6 = 1 + 5 + 12 = 18 \]
\[ \boxed{18 \text{ valence electrons}} \]
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