Questions: Consider a 4d orbital. a. What are the allowed values for the n and l quantum numbers for a 4d orbital? n= b. What are the allowed values for the ml quantum number for a 4d orbital? 0 -1,0,1 -2,-1,0,1,2 -3,-2,-1,0,1,2,3 c. What is the maximum number of 4d orbitals that could be present in any one atom? 4d orbitals d. What is the maximum number of electrons that could occupy a single 4d orbital? electron(s)

Consider a 4d orbital.
a. What are the allowed values for the n and l quantum numbers for a 4d orbital?
n= 
b. What are the allowed values for the ml quantum number for a 4d orbital?
0
-1,0,1
-2,-1,0,1,2
-3,-2,-1,0,1,2,3
c. What is the maximum number of 4d orbitals that could be present in any one atom?
4d orbitals
d. What is the maximum number of electrons that could occupy a single 4d orbital?
electron(s)
Transcript text: Consider a $4 d$ orbital. a. What are the allowed values for the $n$ and $\ell$ quantum numbers for a $4 d$ orbital? $n=$ $\square$ $\square$ b. What are the allowed values for the $m_{\ell}$ quantum number for a $4 d$ orbital? 0 $-1,0,1$ $-2,-1,0,1,2$ $-3,-2,-1,0,1,2,3$ c. What is the maximum number of $4 d$ orbitals that could be present in any one atom? $\square$ $4 d$ orbitals d. What is the maximum number of electrons that could occupy a single $4 d$ orbital? $\square$ electron(s)
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Solution

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Solution Steps

Step 1: Determine the Allowed Values for \( n \) and \( \ell \) Quantum Numbers

For a \( 4d \) orbital:

  • The principal quantum number \( n \) is 4.
  • The azimuthal quantum number \( \ell \) for a \( d \) orbital is 2.

Thus, the allowed values are: \[ n = 4 \] \[ \ell = 2 \]

Step 2: Determine the Allowed Values for \( m_{\ell} \) Quantum Number

The magnetic quantum number \( m_{\ell} \) can take values from \(-\ell\) to \(+\ell\), including zero. For \( \ell = 2 \): \[ m_{\ell} = -2, -1, 0, 1, 2 \]

Step 3: Determine the Maximum Number of \( 4d \) Orbitals

The number of orbitals for a given \( \ell \) value is \( 2\ell + 1 \). For \( \ell = 2 \): \[ 2(2) + 1 = 5 \] So, there are 5 possible \( 4d \) orbitals.

Step 4: Determine the Maximum Number of Electrons in a Single \( 4d \) Orbital

Each orbital can hold a maximum of 2 electrons (one with spin up and one with spin down).

Final Answer

a. The allowed values for the \( n \) and \( \ell \) quantum numbers for a \( 4d \) orbital are: \[ \boxed{n = 4} \] \[ \boxed{\ell = 2} \]

b. The allowed values for the \( m_{\ell} \) quantum number for a \( 4d \) orbital are: \[ \boxed{-2, -1, 0, 1, 2} \]

c. The maximum number of \( 4d \) orbitals that could be present in any one atom is: \[ \boxed{5 \text{ } 4d \text{ orbitals}} \]

d. The maximum number of electrons that could occupy a single \( 4d \) orbital is: \[ \boxed{2 \text{ electron(s)}} \]

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