a. The allowed values for the \( n \) and \( \ell \) quantum numbers for a \( 4d \) orbital are:
\[ \boxed{n = 4} \]
\[ \boxed{\ell = 2} \]
b. The allowed values for the \( m_{\ell} \) quantum number for a \( 4d \) orbital are:
\[ \boxed{-2, -1, 0, 1, 2} \]
c. The maximum number of \( 4d \) orbitals that could be present in any one atom is:
\[ \boxed{5 \text{ } 4d \text{ orbitals}} \]
d. The maximum number of electrons that could occupy a single \( 4d \) orbital is:
\[ \boxed{2 \text{ electron(s)}} \]