Questions: A reaction between liquid reactants takes place at 28.0°C in a sealed, evacuated vessel with a measured volume of 10.0 L. Measurements show that the reaction produced 6.0 g of carbon dioxide gas.
Calculate the pressure of carbon dioxide gas in the reaction vessel after the reaction. You may ignore the volume of the liquid reactants. Round your answer to 2 significant digits.
Transcript text: A reaction between liquid reactants takes place at $28.0^{\circ} \mathrm{C}$ in a sealed, evacuated vessel with a measured volume of 10.0 L. Measurements show that the reaction produced 6.0 g of carbon dioxide gas.
Calculate the pressure of carbon dioxide gas in the reaction vessel after the reaction. You may ignore the volume of the liquid reactants. Round your answer to 2 significant digits.
pressure: $\square$ atm
Solution
Solution Steps
Step 1: Convert Temperature to Kelvin
The temperature given is \(28.0^{\circ} \mathrm{C}\). To use the ideal gas law, we need to convert this temperature to Kelvin using the formula:
\[
T(K) = T(^{\circ}C) + 273.15
\]
\[
T = 28.0 + 273.15 = 301.15 \, \text{K}
\]
Step 2: Calculate Moles of Carbon Dioxide
The mass of carbon dioxide (\(\text{CO}_2\)) is given as 6.0 g. We need to convert this mass to moles using the molar mass of \(\text{CO}_2\), which is approximately 44.01 g/mol:
\[
n = \frac{\text{mass}}{\text{molar mass}} = \frac{6.0 \, \text{g}}{44.01 \, \text{g/mol}} \approx 0.1364 \, \text{mol}
\]
Step 3: Use the Ideal Gas Law to Find Pressure
The ideal gas law is given by:
\[
PV = nRT
\]
where:
\(P\) is the pressure in atm,
\(V\) is the volume in liters,
\(n\) is the number of moles,
\(R\) is the ideal gas constant, \(0.0821 \, \text{L atm/mol K}\),
\(T\) is the temperature in Kelvin.
Rearranging the formula to solve for pressure \(P\):
\[
P = \frac{nRT}{V}
\]
Substituting the known values:
\[
P = \frac{0.1364 \, \text{mol} \times 0.0821 \, \text{L atm/mol K} \times 301.15 \, \text{K}}{10.0 \, \text{L}}
\]
\[
P \approx \frac{3.3685}{10.0} \approx 0.3369 \, \text{atm}
\]
Final Answer
The pressure of carbon dioxide gas in the reaction vessel is approximately \(\boxed{0.34 \, \text{atm}}\).