Questions: Determine the limiting reactant and calculate the number of grams of nitrogen dioxide, NO2, that can be formed when 105 g of nitrogen, N2, reacts with 98.5 g of oxygen, O2. N2(g) + 2 O2(g) → 2 NO2(g)

Determine the limiting reactant and calculate the number of grams of nitrogen dioxide, NO2, that can be formed when 105 g of nitrogen, N2, reacts with 98.5 g of oxygen, O2.

N2(g) + 2 O2(g) → 2 NO2(g)
Transcript text: Determine the limiting reactant and calculate the number of grams of nitrogen dioxide, $\mathrm{NO}_{2}$, that can be formed when 105 g of nitrogen, $\mathrm{N}_{2,}$ reacts with 98.5 g of oxygen, $\mathrm{O}_{2}$. \[ \mathrm{N}_{2}(g)+2 \mathrm{O}_{2}(g) \rightarrow 2 \mathrm{NO}_{2}(g) \]
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Solution

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Solution Steps

Step 1: Calculate Moles of Reactants

First, we need to calculate the number of moles of each reactant. The molar mass of nitrogen (\(\mathrm{N}_2\)) is approximately 28.02 g/mol, and the molar mass of oxygen (\(\mathrm{O}_2\)) is approximately 32.00 g/mol.

For nitrogen: \[ \text{Moles of } \mathrm{N}_2 = \frac{105 \, \text{g}}{28.02 \, \text{g/mol}} \approx 3.748 \, \text{mol} \]

For oxygen: \[ \text{Moles of } \mathrm{O}_2 = \frac{98.5 \, \text{g}}{32.00 \, \text{g/mol}} \approx 3.078 \, \text{mol} \]

Step 2: Determine the Limiting Reactant

The balanced chemical equation is: \[ \mathrm{N}_{2}(g) + 2 \mathrm{O}_{2}(g) \rightarrow 2 \mathrm{NO}_{2}(g) \]

According to the stoichiometry of the reaction, 1 mole of \(\mathrm{N}_2\) reacts with 2 moles of \(\mathrm{O}_2\). Therefore, we need to check which reactant is limiting.

Calculate the required moles of \(\mathrm{O}_2\) for the available \(\mathrm{N}_2\): \[ \text{Required moles of } \mathrm{O}_2 = 3.748 \, \text{mol} \times 2 = 7.496 \, \text{mol} \]

Since we only have 3.078 moles of \(\mathrm{O}_2\), oxygen is the limiting reactant.

Step 3: Calculate the Amount of \(\mathrm{NO}_2\) Formed

Since \(\mathrm{O}_2\) is the limiting reactant, we use its moles to calculate the moles of \(\mathrm{NO}_2\) produced. According to the balanced equation, 2 moles of \(\mathrm{O}_2\) produce 2 moles of \(\mathrm{NO}_2\).

\[ \text{Moles of } \mathrm{NO}_2 = 3.078 \, \text{mol} \times \frac{2 \, \text{mol} \, \mathrm{NO}_2}{2 \, \text{mol} \, \mathrm{O}_2} = 3.078 \, \text{mol} \]

Now, calculate the mass of \(\mathrm{NO}_2\) produced. The molar mass of \(\mathrm{NO}_2\) is approximately 46.01 g/mol.

\[ \text{Mass of } \mathrm{NO}_2 = 3.078 \, \text{mol} \times 46.01 \, \text{g/mol} \approx 141.5 \, \text{g} \]

Final Answer

The limiting reactant is \(\mathrm{O}_2\), and the mass of nitrogen dioxide (\(\mathrm{NO}_2\)) formed is \(\boxed{141.5 \, \text{g}}\).

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