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CHEM 104 ANDINO, F24
Assessments
HW15.1. pH Indicators
When a solution is titrated with an acid, an indicator (In-) changes from blue to yellow (H In). The Ka of the indicator is 2.40 e-06. At what pH will the indicator color change, first be visible?
pH= number (rtol =0.01, atol =1 e-08)
Transcript text: PrairieLearn
CHEM 104 ANDINO, F24
Assessments
HW15.1. pH Indicators
When a solution is titrated with an acid, an indicator ( $\mathrm{In}^{-}$) changes from blue to yellow ( $H I n)$. The $K_{a}$ of the indicator is $2.40 e-06$. At what $p H$ will the indicator color change, first be visible?
$p H=$ number (rtol $=0.01$, atol $=1 \mathrm{e}-08$ )
$\square$
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Solution
Solution Steps
Step 1: Understanding the Problem
We need to determine the pH at which the color change of an indicator becomes visible during a titration. The indicator changes from blue (\(\mathrm{In}^{-}\)) to yellow (\(HIn\)), and the given \(K_a\) of the indicator is \(2.40 \times 10^{-6}\).
Step 2: Using the Henderson-Hasselbalch Equation
The color change of an indicator is typically visible when the concentrations of the acidic form (\(HIn\)) and the basic form (\(\mathrm{In}^{-}\)) are equal. This occurs when the pH of the solution is equal to the pKa of the indicator. The pKa is calculated using the formula:
\[
\text{pKa} = -\log(K_a)
\]
Step 3: Calculating the pKa
Substitute the given \(K_a\) value into the formula:
\[
\text{pKa} = -\log(2.40 \times 10^{-6})
\]
Calculate the pKa:
\[
\text{pKa} \approx 5.6198
\]
Final Answer
The pH at which the indicator color change first becomes visible is approximately: