Questions: Predict the products for the following precipitation reaction:
NiCl2(aq) + (NH4)2 S(aq) ->
NiS(aq) + 2 NH4 Cl(aq)
NiS(s) + 2 NH4 Cl(aq)
NiS(s) + 2 NH4 Cl(s)
NiS(s) + NH4 Cl(aq)
Transcript text: Predict the products for the following precipitation reaction:
\[
\mathrm{NiCl}_{2}(\mathrm{aq})+\left(\mathrm{NH}_{4}\right)_{2} \mathrm{~S}(\mathrm{aq}) \rightarrow
\]
View Available Hint(s)
$\mathrm{NiS}(\mathrm{aq})+2 \mathrm{NH}_{4} \mathrm{Cl}(\mathrm{aq})$
$\mathrm{NiS}(\mathrm{s})+2 \mathrm{NH}_{4} \mathrm{Cl}(\mathrm{aq})$
$\mathrm{NiS}(\mathrm{s})+2 \mathrm{NH}_{4} \mathrm{Cl}(\mathrm{s})$
$\mathrm{NiS}(\mathrm{s})+\mathrm{NH}_{4} \mathrm{Cl}(\mathrm{aq})$
Solution
Solution Steps
Step 1: Identify the reactants and their states
The reactants are \(\mathrm{NiCl}_{2}(\mathrm{aq})\) and \((\mathrm{NH}_{4})_{2} \mathrm{S}(\mathrm{aq})\).
Step 2: Determine the possible products
The possible products are formed by exchanging the ions of the reactants:
\(\mathrm{Ni}^{2+}\) from \(\mathrm{NiCl}_{2}\) and \(\mathrm{S}^{2-}\) from \((\mathrm{NH}_{4})_{2} \mathrm{S}\) form \(\mathrm{NiS}\).
\(\mathrm{NH}_{4}^{+}\) from \((\mathrm{NH}_{4})_{2} \mathrm{S}\) and \(\mathrm{Cl}^{-}\) from \(\mathrm{NiCl}_{2}\) form \(\mathrm{NH}_{4} \mathrm{Cl}\).
Step 3: Determine the states of the products
\(\mathrm{NiS}\) is a solid precipitate (insoluble in water).
\(\mathrm{NH}_{4} \mathrm{Cl}\) is soluble in water and remains in aqueous form.
Step 4: Write the balanced chemical equation
The balanced chemical equation is:
\[
\mathrm{NiCl}_{2}(\mathrm{aq}) + (\mathrm{NH}_{4})_{2} \mathrm{S}(\mathrm{aq}) \rightarrow \mathrm{NiS}(\mathrm{s}) + 2 \mathrm{NH}_{4} \mathrm{Cl}(\mathrm{aq})
\]
Step 5: Select the correct product from the given options
The correct product is:
\[
\mathrm{NiS}(\mathrm{s}) + 2 \mathrm{NH}_{4} \mathrm{Cl}(\mathrm{aq})
\]