Questions: C6H15N 1H NMR a= 6= 13C NMR

C6H15N
1H NMR
a=
6=
13C NMR
Transcript text: 3. $\mathrm{C}_{6} \mathrm{H}_{15} \mathrm{~N}$ 1H NMR $a=$ $6=$ 13C NMR
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Solution

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Solution Steps

Step 1: Determine the Degree of Unsaturation
  • The molecular formula is C6H15N.
  • Degree of unsaturation formula: \( \text{DU} = \frac{2C + 2 - H + N}{2} \)
  • Plugging in the values: \( \text{DU} = \frac{2(6) + 2 - 15 + 1}{2} = \frac{12 + 2 - 15 + 1}{2} = \frac{0}{2} = 0 \)
  • Conclusion: The degree of unsaturation is 0, indicating no double bonds, triple bonds, or rings.
Step 2: Analyze the IR Spectrum
  • The IR spectrum shows peaks around 3300 cm\(^{-1}\) (N-H stretch), 2900 cm\(^{-1}\) (C-H stretch), and 1600 cm\(^{-1}\) (C=C stretch).
  • Conclusion: The presence of N-H and C-H bonds, and possibly an aromatic ring (though DU suggests otherwise).
Step 3: Analyze the 1H NMR Spectrum
  • The 1H NMR spectrum shows peaks at around 0.9 ppm (triplet), 1.2 ppm (multiplet), and 2.7 ppm (quartet).
  • Conclusion: The triplet at 0.9 ppm suggests a CH3 group adjacent to a CH2 group. The quartet at 2.7 ppm suggests a CH2 group adjacent to a CH3 group. The multiplet at 1.2 ppm suggests a CH2 group adjacent to other CH2 groups.

Final Answer

  • The compound is likely a simple amine with no rings or double bonds, consistent with the degree of unsaturation of 0.
  • The IR and NMR spectra suggest the structure is likely a straight-chain amine, such as hexylamine (C6H13NH2).
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