Questions: In each of the following pairs of hydrocarbons, which one would you expect to have the higher boiling point?
Part A
pentane or butane
Transcript text: In each of the following pairs of hydrocarbons, which one would you expect to have the higher boiling point?
Part A
pentane or butane
Solution
Solution Steps
Step 1: Identify the Hydrocarbons
The hydrocarbons in question are pentane and butane.
Step 2: Understand the Boiling Point Concept
The boiling point of a substance is the temperature at which its vapor pressure equals the external pressure. For hydrocarbons, the boiling point generally increases with molecular weight and chain length due to increased van der Waals forces.
Step 3: Compare Molecular Structures
Pentane: C\(_5\)H\(_{12}\), a straight-chain alkane with 5 carbon atoms.
Butane: C\(_4\)H\(_{10}\), a straight-chain alkane with 4 carbon atoms.
Step 4: Determine the Boiling Points
Pentane, having a longer carbon chain than butane, will have stronger van der Waals forces and thus a higher boiling point.