The values are:
- \( C = 0.86 \)
- \( a \approx 1.08 \)
- Estimated gas concentration in 2019 is \( \approx 3.71 \) ppb.
Thus, the final answers are:
\[
\boxed{C = 0.86}
\]
\[
\boxed{a \approx 1.08}
\]
\[
\boxed{\text{Gas concentration in 2019} \approx 3.71 \text{ ppb}}
\]