For the first question, we have a compound containing calcium (Ca) and nitrogen (N). The compound weighs 29.6 g, with 24.0 g of calcium. First, we need to find the moles of each element.
Moles of calcium:
\[
\text{Moles of Ca} = \frac{24.0 \, \text{g}}{40.08 \, \text{g/mol}} = 0.5992 \, \text{mol}
\]
Moles of nitrogen:
\[
\text{Mass of N} = 29.6 \, \text{g} - 24.0 \, \text{g} = 5.6 \, \text{g}
\]
\[
\text{Moles of N} = \frac{5.6 \, \text{g}}{14.01 \, \text{g/mol}} = 0.3997 \, \text{mol}
\]
Next, we find the simplest whole number ratio of moles of calcium to moles of nitrogen.
- Ratio of Ca to N:
\[
\frac{0.5992}{0.3997} \approx 1.5
\]
\[
\frac{0.3997}{0.3997} = 1
\]
To convert to whole numbers, multiply both by 2:
- Ca: \(1.5 \times 2 = 3\)
- N: \(1 \times 2 = 2\)
The empirical formula is based on the whole number ratio of moles:
\[
\text{Empirical formula: } \mathrm{Ca}_3\mathrm{N}_2
\]
For the second question, we have a compound containing sodium (Na), chromium (Cr), and oxygen (O). The sample weighs 170.00 g, with the following masses:
Moles of sodium:
\[
\text{Moles of Na} = \frac{29.84 \, \text{g}}{22.99 \, \text{g/mol}} = 1.2975 \, \text{mol}
\]
Moles of chromium:
\[
\text{Moles of Cr} = \frac{67.49 \, \text{g}}{51.996 \, \text{g/mol}} = 1.2970 \, \text{mol}
\]
Moles of oxygen:
\[
\text{Moles of O} = \frac{72.67 \, \text{g}}{16.00 \, \text{g/mol}} = 4.5419 \, \text{mol}
\]
Find the simplest whole number ratio of moles of each element.
Ratio of Na:
\[
\frac{1.2975}{1.2970} \approx 1
\]
Ratio of Cr:
\[
\frac{1.2970}{1.2970} = 1
\]
Ratio of O:
\[
\frac{4.5419}{1.2970} \approx 3.5
\]
To convert to whole numbers, multiply all by 2:
- Na: \(1 \times 2 = 2\)
- Cr: \(1 \times 2 = 2\)
- O: \(3.5 \times 2 = 7\)
The empirical formula is based on the whole number ratio of moles:
\[
\text{Empirical formula: } \mathrm{Na}_2\mathrm{Cr}_2\mathrm{O}_7
\]
- The empirical formula for the compound of calcium and nitrogen is \(\boxed{\mathrm{Ca}_3\mathrm{N}_2}\).
- The empirical formula for the unidentified compound is \(\boxed{\mathrm{Na}_2\mathrm{Cr}_2\mathrm{O}_7}\).