Questions: Consider these compounds: A. PbI2 B. AgI C. CO(OH)2 D. CaCrO4 Complete the following statements by entering the letter corresponding to the correct compound. Without doing any calculations it is possible to determine that silver chromate is more soluble than , and silver chromate is less soluble than It is not possible to determine whether silver chromate is more or less soluble than by simply comparing Ksp values.

Consider these compounds:
A. PbI2
B. AgI
C. CO(OH)2
D. CaCrO4

Complete the following statements by entering the letter corresponding to the correct compound.

Without doing any calculations it is possible to determine that silver chromate is more soluble than , and silver chromate is less soluble than 
It is not possible to determine whether silver chromate is more or less soluble than by simply comparing Ksp values.
Transcript text: [Review Topics] [References] Use the References to access important values if needed for this question. Consider these compounds: A. $\mathrm{PbI}_{2}$ B. AgI C. $\mathrm{CO}(\mathrm{OH})_{2}$ D. $\mathrm{CaCrO}_{4}$ Complete the following statements by entering the letter corresponding to the correct compound. Without doing any calculations it is possible to determine that silver chromate is more soluble than $\square$ , and silver chromate is less soluble than $\square$ It is not possible to determine whether silver chromate is more or less soluble than $\square$ by simply comparing $\mathrm{K}_{\mathrm{sp}}$ values.
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Solution

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Solution Steps

Step 1: Identify the Compounds

First, identify the compounds given in the question:

  • A. \(\mathrm{PbI}_{2}\) (Lead(II) iodide)
  • B. \(\mathrm{AgI}\) (Silver iodide)
  • C. \(\mathrm{CO(OH)}_{2}\) (Cobalt(II) hydroxide)
  • D. \(\mathrm{CaCrO}_{4}\) (Calcium chromate)
Step 2: Understand the Solubility Context

The question involves comparing the solubility of silver chromate (\(\mathrm{Ag}_2\mathrm{CrO}_4\)) with the given compounds. Solubility is often compared using the solubility product constant (\(K_{\mathrm{sp}}\)).

Step 3: Determine Solubility Relationships
  • More Soluble than Silver Chromate: Compounds with a higher \(K_{\mathrm{sp}}\) than silver chromate are more soluble.
  • Less Soluble than Silver Chromate: Compounds with a lower \(K_{\mathrm{sp}}\) than silver chromate are less soluble.
  • Indeterminate Solubility: If \(K_{\mathrm{sp}}\) values are not directly comparable or not provided, solubility cannot be determined.
Step 4: Apply the Information
  • More Soluble than Silver Chromate: Without specific \(K_{\mathrm{sp}}\) values, we assume that \(\mathrm{CaCrO}_{4}\) (D) is more soluble because chromates are generally more soluble than iodides.
  • Less Soluble than Silver Chromate: \(\mathrm{AgI}\) (B) is typically less soluble than silver chromate.
  • Indeterminate Solubility: \(\mathrm{PbI}_{2}\) (A) and \(\mathrm{CO(OH)}_{2}\) (C) cannot be directly compared without specific \(K_{\mathrm{sp}}\) values.

Final Answer

  • Silver chromate is more soluble than \(\boxed{\mathrm{AgI}}\).
  • Silver chromate is less soluble than \(\boxed{\mathrm{CaCrO}_{4}}\).
  • It is not possible to determine whether silver chromate is more or less soluble than \(\boxed{\mathrm{PbI}_{2}}\) by simply comparing \(K_{\mathrm{sp}}\) values.
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