Balance the chemical reaction using an atom inventory.
Identify the number of atoms of each element on both sides of the equation.
On the left side of the equation:
- Aluminum (\(\mathrm{Al}\)): 1 atom
- Chlorine (\(\mathrm{Cl}\)): 2 atoms (from \(\mathrm{Cl}_2\))
On the right side of the equation:
- Aluminum (\(\mathrm{Al}\)): 1 atom (from \(\mathrm{AlCl}_3\))
- Chlorine (\(\mathrm{Cl}\)): 3 atoms (from \(\mathrm{AlCl}_3\))
Balance the aluminum atoms.
The number of aluminum atoms is already balanced with 1 atom on both sides.
Balance the chlorine atoms.
To balance the chlorine atoms, we need to have the same number of chlorine atoms on both sides. Since \(\mathrm{Cl}_2\) has 2 chlorine atoms and \(\mathrm{AlCl}_3\) has 3 chlorine atoms, we need to find a common multiple of 2 and 3, which is 6.
Thus, we need 3 \(\mathrm{Cl}_2\) molecules to get 6 chlorine atoms on the left side and 2 \(\mathrm{AlCl}_3\) molecules to get 6 chlorine atoms on the right side.
The updated equation is:
\[
\mathrm{Al} + 3\mathrm{Cl}_2 \rightarrow 2\mathrm{AlCl}_3
\]
Balance the aluminum atoms again.
Now, we have 2 aluminum atoms on the right side (from 2 \(\mathrm{AlCl}_3\)), so we need 2 aluminum atoms on the left side.
The final balanced equation is:
\[
2\mathrm{Al} + 3\mathrm{Cl}_2 \rightarrow 2\mathrm{AlCl}_3
\]
The coefficient for chlorine, \(\mathrm{Cl}_2\), is \(\boxed{3}\).
The coefficient for chlorine, \(\mathrm{Cl}_2\), is \(\boxed{3}\).