Questions: Now examine salts containing the halide anions, Cl^- and Br-. Most of these are soluble. What two cations listed lead to insoluble halide salts?
Transcript text: Now examine salts containing the halide anions, $\mathrm{Cl}^{-}$and Br$^{-}$. Most of these are soluble. What two cations listed lead to insoluble halide salts?
Solution
Solution Steps
Step 1: Identify the Halide Anions
The halide anions mentioned in the question are chloride (\(\mathrm{Cl}^{-}\)) and bromide (\(\mathrm{Br}^{-}\)).
Step 2: Review the Solubility Rules for Halides
In general, most halide salts are soluble in water. However, there are exceptions, particularly with certain cations. Common exceptions include salts containing silver (\(\mathrm{Ag}^{+}\)), lead (\(\mathrm{Pb}^{2+}\)), and mercury (\(\mathrm{Hg}_2^{2+}\)).
Step 3: Identify Cations Leading to Insoluble Halide Salts
From the table provided, we need to identify which cations form insoluble salts with the halide anions (\(\mathrm{Cl}^{-}\) and \(\mathrm{Br}^{-}\)).
Silver (\(\mathrm{Ag}^{+}\)): Known to form insoluble salts with halides such as \(\mathrm{AgCl}\) and \(\mathrm{AgBr}\).
Lead (\(\mathrm{Pb}^{2+}\)): Known to form insoluble salts with halides such as \(\mathrm{PbCl}_2\) and \(\mathrm{PbBr}_2\).
Final Answer
\[
\boxed{\mathrm{Ag}^{+} \text{ and } \mathrm{Pb}^{2+}}
\]