Questions: Now examine salts containing the halide anions, Cl^- and Br-. Most of these are soluble. What two cations listed lead to insoluble halide salts?

Now examine salts containing the halide anions, Cl^- and Br-. Most of these are soluble. What two cations listed lead to insoluble halide salts?
Transcript text: Now examine salts containing the halide anions, $\mathrm{Cl}^{-}$and Br$^{-}$. Most of these are soluble. What two cations listed lead to insoluble halide salts?
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Solution

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Solution Steps

Step 1: Identify the Halide Anions

The halide anions mentioned in the question are chloride (\(\mathrm{Cl}^{-}\)) and bromide (\(\mathrm{Br}^{-}\)).

Step 2: Review the Solubility Rules for Halides

In general, most halide salts are soluble in water. However, there are exceptions, particularly with certain cations. Common exceptions include salts containing silver (\(\mathrm{Ag}^{+}\)), lead (\(\mathrm{Pb}^{2+}\)), and mercury (\(\mathrm{Hg}_2^{2+}\)).

Step 3: Identify Cations Leading to Insoluble Halide Salts

From the table provided, we need to identify which cations form insoluble salts with the halide anions (\(\mathrm{Cl}^{-}\) and \(\mathrm{Br}^{-}\)).

  • Silver (\(\mathrm{Ag}^{+}\)): Known to form insoluble salts with halides such as \(\mathrm{AgCl}\) and \(\mathrm{AgBr}\).
  • Lead (\(\mathrm{Pb}^{2+}\)): Known to form insoluble salts with halides such as \(\mathrm{PbCl}_2\) and \(\mathrm{PbBr}_2\).

Final Answer

\[ \boxed{\mathrm{Ag}^{+} \text{ and } \mathrm{Pb}^{2+}} \]

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