To solve the given mathematical expression, we need to perform the multiplication first, followed by the subtraction. This involves calculating \(10.114 \times 0.543\) and then subtracting \(102.11\) from the result.
Step 1: Calculate the Multiplication
We start by calculating the product of \(10.114\) and \(0.543\):
\[
10.114 \times 0.543 = 5.4919
\]
Step 2: Perform the Subtraction
Next, we subtract \(102.11\) from the result obtained in Step 1:
\[
5.4919 - 102.11 = -96.6181
\]
Final Answer
The final result of the expression \(10.114 \times 0.543 - 102.11\) is
\[
\boxed{-96.6181}
\]