The reaction involves solid aluminum (\(\mathrm{Al}(s)\)) and hydrochloric acid (\(\mathrm{HCl}(aq)\)). Aluminum reacts with hydrochloric acid to produce aluminum chloride and hydrogen gas. The balanced chemical equation is:
\[
2\mathrm{Al}(s) + 6\mathrm{HCl}(aq) \rightarrow 2\mathrm{AlCl}_3(aq) + 3\mathrm{H}_2(g)
\]
In aqueous solution, \(\mathrm{HCl}\) dissociates into \(\mathrm{H}^+\) and \(\mathrm{Cl}^-\) ions, and \(\mathrm{AlCl}_3\) dissociates into \(\mathrm{Al}^{3+}\) and \(\mathrm{Cl}^-\) ions. The ionic equation is:
\[
2\mathrm{Al}(s) + 6\mathrm{H}^+(aq) + 6\mathrm{Cl}^-(aq) \rightarrow 2\mathrm{Al}^{3+}(aq) + 6\mathrm{Cl}^-(aq) + 3\mathrm{H}_2(g)
\]
Cancel out the spectator ions (\(\mathrm{Cl}^-\)) that appear on both sides of the equation:
\[
2\mathrm{Al}(s) + 6\mathrm{H}^+(aq) \rightarrow 2\mathrm{Al}^{3+}(aq) + 3\mathrm{H}_2(g)
\]
The reaction involves silver nitrate (\(\mathrm{AgNO}_3(aq)\)) and phosphoric acid (\(\mathrm{H}_3\mathrm{PO}_4(aq)\)). Silver phosphate (\(\mathrm{Ag}_3\mathrm{PO}_4\)) is insoluble in water and will precipitate. The balanced chemical equation is:
\[
3\mathrm{AgNO}_3(aq) + \mathrm{H}_3\mathrm{PO}_4(aq) \rightarrow \mathrm{Ag}_3\mathrm{PO}_4(s) + 3\mathrm{HNO}_3(aq)
\]
In aqueous solution, \(\mathrm{AgNO}_3\) dissociates into \(\mathrm{Ag}^+\) and \(\mathrm{NO}_3^-\) ions, and \(\mathrm{H}_3\mathrm{PO}_4\) dissociates into \(\mathrm{H}^+\) and \(\mathrm{PO}_4^{3-}\) ions. The ionic equation is:
\[
3\mathrm{Ag}^+(aq) + 3\mathrm{NO}_3^-(aq) + 3\mathrm{H}^+(aq) + \mathrm{PO}_4^{3-}(aq) \rightarrow \mathrm{Ag}_3\mathrm{PO}_4(s) + 3\mathrm{H}^+(aq) + 3\mathrm{NO}_3^-(aq)
\]
Cancel out the spectator ions (\(\mathrm{NO}_3^-\) and \(\mathrm{H}^+\)) that appear on both sides of the equation:
\[
3\mathrm{Ag}^+(aq) + \mathrm{PO}_4^{3-}(aq) \rightarrow \mathrm{Ag}_3\mathrm{PO}_4(s)
\]
- Part 1: \(\boxed{2\mathrm{Al}(s) + 6\mathrm{H}^+(aq) \rightarrow 2\mathrm{Al}^{3+}(aq) + 3\mathrm{H}_2(g)}\)
- Part 2: \(\boxed{3\mathrm{Ag}^+(aq) + \mathrm{PO}_4^{3-}(aq) \rightarrow \mathrm{Ag}_3\mathrm{PO}_4(s)}\)