Questions: Determine the density of NH3 gas at 435 K and 1.00 atm. A) 0.851 g / L B) 0.321 g / L C) 0.477 g / L D) 2.10 g / L E) 2.24 g / L A sample of nitrogen gas had a volume of 500 mL, a pressure in its container of 740 Torr, and a temperature of 25°C. What was the new volume of the gas when the temperature was changed to 50°C and the new pressure was 760 Tom? A) 528 mL B) 408 mL C) 244 mL D) 452 mL E) 976 mL

Determine the density of NH3 gas at 435 K and 1.00 atm.
A) 0.851 g / L
B) 0.321 g / L
C) 0.477 g / L
D) 2.10 g / L
E) 2.24 g / L

A sample of nitrogen gas had a volume of 500 mL, a pressure in its container of 740 Torr, and a temperature of 25°C. What was the new volume of the gas when the temperature was changed to 50°C and the new pressure was 760 Tom?
A) 528 mL
B) 408 mL
C) 244 mL
D) 452 mL
E) 976 mL
Transcript text: Determine the density of $\mathrm{NH}_{3}$ gas at 435 K and 1.00 atm . A) $0.851 \mathrm{~g} / \mathrm{L}$ B) $0.321 \mathrm{~g} / \mathrm{L}$ C) $0.477 \mathrm{~g} / \mathrm{L}$ D) $2.10 \mathrm{~g} / \mathrm{L}$ E) $2.24 \mathrm{~g} / \mathrm{L}$ A sample of nitrogen gas had a volume of $500 . \mathrm{mL}$, a pressure in its container of 740 . Torr, and a temperature of $25^{\circ} \mathrm{C}$. What was the new volume of the gas when the temperature was changed to $50^{\circ} \mathrm{C}$ and the new pressure was $760 . \mathrm{Tom}$ ? A) 528 mL B) 408 mL C) 244 mL D) 452 mL E) 976 mL
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Solution

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Solution Steps

Step 1: Determine the Density of NH\(_3\) Gas

To find the density of NH\(_3\) gas at 435 K and 1.00 atm, we use the ideal gas law in the form of the density equation:

\[ \text{Density} = \frac{PM}{RT} \]

where:

  • \(P\) is the pressure (1.00 atm),
  • \(M\) is the molar mass of NH\(_3\) (17.031 g/mol),
  • \(R\) is the ideal gas constant (0.0821 L·atm/(K·mol)),
  • \(T\) is the temperature (435 K).
Step 2: Substitute the Values into the Density Equation

Substitute the given values into the equation:

\[ \text{Density} = \frac{(1.00 \, \text{atm}) \times (17.031 \, \text{g/mol})}{(0.0821 \, \text{L·atm/(K·mol)}) \times (435 \, \text{K})} \]

Step 3: Calculate the Density

Perform the calculation:

\[ \text{Density} = \frac{17.031}{35.7255} \approx 0.4767 \, \text{g/L} \]

Final Answer for Density of NH\(_3\) Gas

\(\boxed{0.477 \, \text{g/L}}\)

Step 1: Determine the New Volume of Nitrogen Gas

To find the new volume of the nitrogen gas when the temperature and pressure change, we use the combined gas law:

\[ \frac{P_1 V_1}{T_1} = \frac{P_2 V_2}{T_2} \]

where:

  • \(P_1 = 740 \, \text{Torr}\),
  • \(V_1 = 500 \, \text{mL}\),
  • \(T_1 = 25^\circ \text{C} = 298 \, \text{K}\),
  • \(P_2 = 760 \, \text{Torr}\),
  • \(T_2 = 50^\circ \text{C} = 323 \, \text{K}\),
  • \(V_2\) is the new volume.
Step 2: Rearrange the Combined Gas Law to Solve for \(V_2\)

Rearrange the equation to solve for \(V_2\):

\[ V_2 = V_1 \times \frac{P_1}{P_2} \times \frac{T_2}{T_1} \]

Step 3: Substitute the Values into the Equation

Substitute the given values into the equation:

\[ V_2 = 500 \, \text{mL} \times \frac{740 \, \text{Torr}}{760 \, \text{Torr}} \times \frac{323 \, \text{K}}{298 \, \text{K}} \]

Step 4: Calculate the New Volume

Perform the calculation:

\[ V_2 = 500 \times 0.9737 \times 1.0839 \approx 528.1 \, \text{mL} \]

Final Answer for New Volume of Nitrogen Gas

\(\boxed{528 \, \text{mL}}\)

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