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The standard heat of formation for NiCl2(s) is -305 kJ / mol at 298 K. Write the formation equation for NiCl2(s) that goes with this value of ΔH°.
Be sure to specify states. Write fractions with a slash, such as 1 / 2 for one half. If a box is not needed leave it blank.
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Transcript text: Use the References to access important values if needed for this question.
The standard heat of formation for $\mathrm{NiCl}_{2}(\mathrm{~s})$ is $-305 \mathrm{~kJ} / \mathrm{mol}$ at 298 K . Write the formation equation for $\mathrm{NiCl}_{2}(\mathrm{~s})$ that goes with this value of $\Delta \mathrm{H}^{\circ}$.
Be sure to specify states. Write fractions with a slash, such as $1 / 2$ for one half. If a box is not needed leave it blank.
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$\square$
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Solution
Solution Steps
Step 1: Understand the Concept of Standard Heat of Formation
The standard heat of formation (\(\Delta H_f^\circ\)) of a compound is the change in enthalpy when one mole of the compound is formed from its elements in their standard states. For \(\mathrm{NiCl}_2(\mathrm{s})\), this means forming solid nickel(II) chloride from solid nickel and gaseous chlorine.
Step 2: Identify the Elements and Their Standard States
The elements involved in the formation of \(\mathrm{NiCl}_2(\mathrm{s})\) are nickel (Ni) and chlorine (Cl). The standard state of nickel is solid (\(\mathrm{Ni(s)}\)), and the standard state of chlorine is diatomic gas (\(\mathrm{Cl}_2(\mathrm{g})\)).
Step 3: Write the Balanced Formation Equation
The formation equation for \(\mathrm{NiCl}_2(\mathrm{s})\) from its elements in their standard states is:
\[
\mathrm{Ni(s)} + \mathrm{Cl}_2(\mathrm{g)} \rightarrow \mathrm{NiCl}_2(\mathrm{s)}
\]
Step 4: Ensure the Equation Matches the Heat of Formation
The equation should represent the formation of exactly one mole of \(\mathrm{NiCl}_2(\mathrm{s})\). The stoichiometry is already correct, as one mole of \(\mathrm{NiCl}_2(\mathrm{s})\) is formed from one mole of \(\mathrm{Ni(s)}\) and one mole of \(\mathrm{Cl}_2(\mathrm{g)}\).
Final Answer
The formation equation for \(\mathrm{NiCl}_2(\mathrm{s})\) is:
\[
\boxed{\mathrm{Ni(s)} + \mathrm{Cl}_2(\mathrm{g)} \rightarrow \mathrm{NiCl}_2(\mathrm{s)}}
\]