The magnitude of the sum \(\vec{C} = \vec{A} + \vec{B}\) is maximum when the two vectors are parallel and minimum when they are anti-parallel.
\[
\boxed{|\vec{C}|_{\text{max}} = |\vec{A}| + |\vec{B}|}
\]
\[
\boxed{|\vec{C}|_{\text{min}} = ||\vec{A}| - |\vec{B}||}
\]