Coffee is known to be slightly acidic. The pH scale is used to measure the acidity or basicity of a solution, where a pH less than 7 indicates an acidic solution. The concentration of hydrogen ions, \([\mathrm{H}^+]\), in a solution is related to its pH by the formula:
\[
\text{pH} = -\log_{10} [\mathrm{H}^+]
\]
For a slightly acidic solution like coffee, the pH is typically around 4 to 5.
Given that coffee is slightly acidic with a pH around 4 to 5, we can estimate the concentration of \([\mathrm{H}^+]\) using the formula:
\[
[\mathrm{H}^+] = 10^{-\text{pH}}
\]
For a pH of 5, the concentration of \([\mathrm{H}^+]\) would be:
\[
[\mathrm{H}^+] = 10^{-5}
\]
From the given options, the concentration of \([\mathrm{H}^+]\) that corresponds to a slightly acidic solution like coffee is \(10^{-5}\).