Sulfur (S) has an atomic number of 16, which means it has 16 protons and, in its neutral state, 16 electrons.
The ion \(\mathrm{S}^{2-}\) has gained 2 additional electrons, making the total number of electrons 18.
To write the electron configuration, we fill the orbitals in the order of increasing energy levels:
The full electron configuration for \(\mathrm{S}^{2-}\) is: \[ \boxed{1s^2 \, 2s^2 \, 2p^6 \, 3s^2 \, 3p^6} \]
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