The mass of oxygen required is \(\boxed{4.0032 \, \text{g}}\).
For the second question, we need the molar masses of aluminum (Al) and sulfur (S):
- Aluminum (Al): 26.98 g/mol
- Sulfur (S): 32.07 g/mol
The formula for aluminum sulfide is \(\text{Al}_2\text{S}_3\).
The reaction between aluminum and sulfur is:
\[ 2 \text{Al} + 3 \text{S} \rightarrow \text{Al}_2\text{S}_3 \]
Convert the mass of aluminum sulfide to moles:
\[
\text{Molar mass of } \text{Al}_2\text{S}_3 = 2(26.98) + 3(32.07) = 150.14 \, \text{g/mol}
\]
\[
\text{Moles of } \text{Al}_2\text{S}_3 = \frac{272.4 \, \text{kg} \times 1000 \, \text{g/kg}}{150.14 \, \text{g/mol}} = 1814.3 \, \text{mol}
\]
From the balanced equation, 1 mole of \(\text{Al}_2\text{S}_3\) requires 3 moles of sulfur. Therefore, the moles of sulfur required are:
\[
\text{Moles of S} = 1814.3 \, \text{mol} \times \frac{3 \, \text{mol S}}{1 \, \text{mol } \text{Al}_2\text{S}_3} = 5442.9 \, \text{mol S}
\]
Now, calculate the mass of sulfur required:
\[
\text{Mass of S} = 5442.9 \, \text{mol} \times 32.07 \, \text{g/mol} = 174,500 \, \text{g} = 174.5 \, \text{kg}
\]
The mass of sulfur required is \(\boxed{174.5 \, \text{kg}}\).