Questions: Consider the electron configuration of the ion to determine which ion shown below has an incorrect ionic charge?
Ba^2+
Rb^+
Al^3-
Se^2-
Transcript text: Consider the electron configuration of the ion to determine which ion shown below has an incorrect ionic charge?
$\mathrm{Ba}^{2+}$
$\mathrm{Rb}^{+}$
$\mathrm{Al}^{3-}$
$\mathrm{Se}^{2-}$
Solution
Solution Steps
Step 1: Determine the Electron Configuration of Each Ion
To determine if the ionic charge is correct, we need to compare the electron configuration of each ion to its neutral atom.
Barium (Ba): Neutral barium has an atomic number of 56, so its electron configuration is:
\[
\mathrm{Ba}: [Xe] 6s^2
\]
For \(\mathrm{Ba}^{2+}\), it loses 2 electrons:
\[
\mathrm{Ba}^{2+}: [Xe]
\]
Rubidium (Rb): Neutral rubidium has an atomic number of 37, so its electron configuration is:
\[
\mathrm{Rb}: [Kr] 5s^1
\]
For \(\mathrm{Rb}^{+}\), it loses 1 electron:
\[
\mathrm{Rb}^{+}: [Kr]
\]
Aluminum (Al): Neutral aluminum has an atomic number of 13, so its electron configuration is:
\[
\mathrm{Al}: [Ne] 3s^2 3p^1
\]
For \(\mathrm{Al}^{3-}\), it gains 3 electrons:
\[
\mathrm{Al}^{3-}: [Ne] 3s^2 3p^4
\]
Selenium (Se): Neutral selenium has an atomic number of 34, so its electron configuration is:
\[
\mathrm{Se}: [Ar] 4s^2 3d^{10} 4p^4
\]
For \(\mathrm{Se}^{2-}\), it gains 2 electrons:
\[
\mathrm{Se}^{2-}: [Ar] 4s^2 3d^{10} 4p^6
\]
Step 2: Verify the Correctness of Each Ionic Charge
\(\mathrm{Ba}^{2+}\): The electron configuration \([Xe]\) is correct for \(\mathrm{Ba}^{2+}\), as it loses 2 electrons.
\(\mathrm{Rb}^{+}\): The electron configuration \([Kr]\) is correct for \(\mathrm{Rb}^{+}\), as it loses 1 electron.
\(\mathrm{Al}^{3-}\): The electron configuration \([Ne] 3s^2 3p^4\) is incorrect for \(\mathrm{Al}^{3-}\). Aluminum typically forms a \(3+\) ion, not a \(3-\) ion.
\(\mathrm{Se}^{2-}\): The electron configuration \([Ar] 4s^2 3d^{10} 4p^6\) is correct for \(\mathrm{Se}^{2-}\), as it gains 2 electrons.