First, we need to calculate the number of moles of each gas in the sample.
For methane (\(\mathrm{CH}_4\)):
For helium (\(\mathrm{He}\)):
Add the moles of \(\mathrm{CH}_4\) and \(\mathrm{He}\) to find the total number of moles in the gas sample:
\[ \text{Total moles} = 0.2492 \, \text{mol} + 0.5000 \, \text{mol} = 0.7492 \, \text{mol} \]
At standard temperature and pressure (STP), 1 mole of an ideal gas occupies 22.4 liters. Therefore, the volume of the gas sample can be calculated as follows:
\[ \text{Volume} = 0.7492 \, \text{mol} \times 22.4 \, \text{L/mol} = 16.78 \, \text{L} \]
The volume of the gas sample at STP is approximately \(\boxed{17 \, \text{L}}\).
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