Questions: How many unpaired electrons are there in the following ground-state atoms and ions? If none, enter a zero in the answer box.
O has unpaired electrons
P3- has unpaired electrons
Transcript text: How many unpaired electrons are there in the following ground-state atoms and ions? If none, enter a zero in the answer box.
O has $\square$ unpaired electrons
$\mathrm{P}^{3-}$ has $\square$ unpaired electrons
Solution
Solution Steps
Step 1: Determine the Electron Configuration of Oxygen (O)
Oxygen (O) has an atomic number of 8.
The electron configuration for oxygen is \(1s^2 \, 2s^2 \, 2p^4\).
Step 2: Identify Unpaired Electrons in Oxygen
The \(2p\) subshell can hold a maximum of 6 electrons.
In oxygen, the \(2p\) subshell has 4 electrons: \(2p^4\).
Electrons fill orbitals singly before pairing up (Hund's rule).
Therefore, in the \(2p\) subshell, there are 2 unpaired electrons.
Step 3: Determine the Electron Configuration of \(\mathrm{P}^{3-}\)
Phosphorus (P) has an atomic number of 15.
The electron configuration for neutral phosphorus is \(1s^2 \, 2s^2 \, 2p^6 \, 3s^2 \, 3p^3\).
The \(\mathrm{P}^{3-}\) ion has gained 3 additional electrons, making the configuration \(1s^2 \, 2s^2 \, 2p^6 \, 3s^2 \, 3p^6\).
Step 4: Identify Unpaired Electrons in \(\mathrm{P}^{3-}\)
The \(3p\) subshell in \(\mathrm{P}^{3-}\) is fully filled with 6 electrons: \(3p^6\).
A fully filled subshell has no unpaired electrons.
Therefore, \(\mathrm{P}^{3-}\) has 0 unpaired electrons.
Final Answer
O has \( \boxed{2} \) unpaired electrons.
\(\mathrm{P}^{3-}\) has \( \boxed{0} \) unpaired electrons.