The least acidic species is \(\boxed{\text{CH}_4}\).
The electronic configuration of an atom or ion is determined by the distribution of electrons in its atomic orbitals.
- Neutral Sodium (Na): The atomic number of sodium is 11, so its electronic configuration is \(1s^2 2s^2 2p^6 3s^1\).
- Na⁺ Ion: The Na⁺ ion has lost one electron compared to the neutral atom. Therefore, the electronic configuration of Na⁺ is \(1s^2 2s^2 2p^6\).
The electronic configuration of \(\mathrm{Na}^+\) is \(\boxed{1s^2 2s^2 2p^6}\).