Questions: Hydrochloric acid is typically purchased in a relatively highly concentrated form and then diluted by adding slowly to water to save money. The concentration of the purchased solution is 37.0% by mass HCl, and this solution has a density of 1.20 g/mL. What volume of the concentrated HCl solution is the correct amount needed to make 3.7 L of 0.435 M HCl? - 130 mL - 8.5 mL - 12 mL - 1.1 L - 96 mL

Hydrochloric acid is typically purchased in a relatively highly concentrated form and then diluted by adding slowly to water to save money. The concentration of the purchased solution is 37.0% by mass HCl, and this solution has a density of 1.20 g/mL.

What volume of the concentrated HCl solution is the correct amount needed to make 3.7 L of 0.435 M HCl? 
- 130 mL 
- 8.5 mL 
- 12 mL 
- 1.1 L 
- 96 mL
Transcript text: 12. Hydrochloric acid is typically purchased in a relatively highly concentrated form and then diluted by adding slowly to water to save money. The concentration of the purchased solution is $37.0 \%$ by mass HCl , and this solution has a density of $1.20 \mathrm{~g} / \mathrm{mL}$. What volume of the concentrated HCl solution is the correct amount needed to make 3.7 L of 0.435 MHCl ? 130 mL 8.5 mL 12 mL 1.1 L 96 mL
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Solution

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Solution Steps

Step 1: Calculate the moles of HCl needed
  • Use the formula \( M = \frac{n}{V} \) where \( M \) is molarity, \( n \) is moles, and \( V \) is volume in liters.
  • Given \( M = 0.435 \, \text{M} \) and \( V = 3.7 \, \text{L} \): \[ n = M \times V = 0.435 \, \text{M} \times 3.7 \, \text{L} = 1.6095 \, \text{moles} \]
Step 2: Calculate the mass of HCl needed
  • Use the molar mass of HCl (\( 36.46 \, \text{g/mol} \)): \[ \text{Mass of HCl} = 1.6095 \, \text{moles} \times 36.46 \, \text{g/mol} = 58.67 \, \text{g} \]
Step 3: Calculate the volume of the concentrated HCl solution needed
  • The concentrated solution is \( 37.0\% \) by mass HCl, so: \[ \text{Mass of solution} = \frac{58.67 \, \text{g}}{0.37} = 158.57 \, \text{g} \]
  • Use the density of the concentrated solution (\( 1.20 \, \text{g/mL} \)): \[ \text{Volume of solution} = \frac{158.57 \, \text{g}}{1.20 \, \text{g/mL}} = 132.14 \, \text{mL} \]
Step 4: Select the closest answer
  • The closest answer to \( 132.14 \, \text{mL} \) is \( 130 \, \text{mL} \).

Final Answer

\(\boxed{130 \, \text{mL}}\)

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