Questions: Which acid/base pair will give an equivalence point above a pH of 7?
Select the correct answer below:
NaOH and HCl
NH3 and HCl
NH3 and CH3COOH
NaOH and CH3COOH
Transcript text: knewton.com
Unit 6.3 - Buffers - Knewton
Unit 6.4 - Titrations | Knewton
CURRENT OBJECTIVE Interpret titration curves
First up, let's review the assignment's learning objectives
Get familiar with this topic by reviewing instruction and answering a couple of questions.
Question
Which acid/base pair will give an equivalence point above a pH of 7 ?
Select the correct answer below:
NaOH and HCl
$\mathrm{NH}_{3}$ and HCl
$\mathrm{NH}_{3}$ and $\mathrm{CH}_{3} \mathrm{COOH}$
NaOH and $\mathrm{CH}_{3} \mathrm{COOH}$
Solution
Solution Steps
Step 1: Understand the Concept of Equivalence Point
The equivalence point in a titration is where the amount of acid equals the amount of base. For strong acid-strong base titrations, the equivalence point is typically at pH 7. For weak acid-strong base titrations, the equivalence point is above pH 7 because the conjugate base of the weak acid will hydrolyze to form OH\(^-\) ions, making the solution basic.
Step 2: Analyze Each Acid/Base Pair
NaOH and HCl: Both are strong, so the equivalence point will be at pH 7.
NH\(_3\) and HCl: NH\(_3\) is a weak base and HCl is a strong acid, so the equivalence point will be below pH 7.
NH\(_3\) and CH\(_3\)COOH: NH\(_3\) is a weak base and CH\(_3\)COOH is a weak acid. The equivalence point will depend on the relative strengths of the weak acid and weak base, but it is typically around pH 7.
NaOH and CH\(_3\)COOH: NaOH is a strong base and CH\(_3\)COOH is a weak acid, so the equivalence point will be above pH 7.
Step 3: Select the Correct Answer
Based on the analysis, the pair that will give an equivalence point above a pH of 7 is NaOH and CH\(_3\)COOH.
Final Answer
\(\boxed{\text{NaOH and } \mathrm{CH}_{3} \mathrm{COOH}}\)