Questions: Which one of the following structures produced the following IR spectrum?

Which one of the following structures produced the following IR spectrum?
Transcript text: Which one of the following structures produced the following IR spectrum?
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Solution

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Solution Steps

Step 1: Identify Key Peaks in the IR Spectrum
  • The IR spectrum shows significant peaks around 1700 cm⁻¹, 3000 cm⁻¹, and 1200 cm⁻¹.
  • The peak around 1700 cm⁻¹ is indicative of a carbonyl (C=O) stretch.
  • The peaks around 3000 cm⁻¹ suggest the presence of C-H stretches.
  • The peak around 1200 cm⁻¹ could be due to C-O stretches.
Step 2: Compare Peaks with Functional Groups in Given Structures
  • Option A: Contains a triple bond (C≡C), which would show a peak around 2100-2260 cm⁻¹ (not present in the spectrum).
  • Option B: Contains only C-H and C-C bonds, which would not show a significant peak around 1700 cm⁻¹.
  • Option C: Contains a carbonyl group (C=O), which matches the peak around 1700 cm⁻¹.
  • Option D: Contains a nitrile group (C≡N), which would show a peak around 2200-2260 cm⁻¹ (not present in the spectrum).
Step 3: Match the Spectrum to the Correct Structure
  • The spectrum shows a strong peak around 1700 cm⁻¹, which is characteristic of a carbonyl group.
  • Only Option C has a carbonyl group, which matches the observed IR spectrum.

Final Answer

C

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